Electromechanical
Early power conversion systems were purely electro-mechanical in design, since electronic devices were not available to handle significant power. Mechanical rectification systems usually rely on some form of rotation or resonant vibration in order to move quickly enough to match the frequency of the input power source, and cannot operate beyond several thousand cycles per second.
Due to the complexity of mechanical systems, they have traditionally needed a high level of maintenance to keep operating correctly. Moving parts will have friction, which requires lubrication and replacement due to wear. Opening mechanical contacts under load results in electrical arcs and sparks that heat and erode the contacts.
Synchronous rectifier
To convert AC currents into DC current in electronic locomotive, a synchronous rectifier may be used. It consists of a synchronous motor driving a set of heavy-duty electrical contacts. The motor spins in time with the AC frequency and periodically reverses the connections to the load just when the sinusoidal current goes through a zero-crossing. The contacts do not have to switch a large current, but they need to be able to carry a large current to supply the locomotive's DC traction motors.Vibrator
In the past, the vibrators used in battery-to-high-voltage-DC power supplies often contained a second set of contacts that performed synchronous mechanical rectification of the stepped-up voltage.
Motor-generator set
A motor-generator set or the similar rotary converter, is not a rectifier in the sense that it doesn't actually rectify current, but rather generates DC from an AC source. In an "M-G set", the shaft of an AC motor is mechanically coupled to that of a DC generator. The DC generator produces multiphase alternating currents in its armature windings, and a commutator on the armature shaft converts these alternating currents into a direct current output; or a homopolar generator produces a direct current without the need for a commutator. M-G sets are useful for producing DC for railway traction motors, industrial motors and other high-current applications, and were common in many high power D.C. uses (for example, carbon-arc lamp projectors for outdoor theaters) before high-power semiconductors became widely available.
Electrolytic
The electrolytic rectifier was an early device from the 1900s that is now no longer used. When two different metals are suspended in an electrolyte solution, it can be found that direct current flowing one way through the metals has less resistance than the other direction. These most commonly used an aluminum anode, and a lead or steel cathode, suspended in a solution of tri-ammonium ortho-phosphate.
The rectification action is due to a thin coating of aluminum hydroxide on the aluminum electrode, formed by first applying a strong current to the cell to build up the coating. The rectification process is temperature sensitive, and for best efficiency should not operate above 86 °F (30 °C). There is also a breakdown voltage where the coating is penetrated and the cell is short-circuited. Electrochemical methods are often more fragile than mechanical methods, and can be sensitive to usage variations which can drastically change or completely disrupt the rectification processes.
Similar electrolytic devices were used as lightning arresters around the same era by suspending many aluminium cones in a tank of tri-ammomium ortho-phosphate solution. Unlike the rectifier, above, only aluminium electrodes were used, and used on A.C., there was no polarization and thus no rectifier action, but the chemistry was similar.
The modern electrolytic capacitor, an essential component of most rectifier circuit configurations was also developed from the electrolytic rectifier.
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